Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors.

نویسندگان

  • Íñigo Aguirre de Carcer García
  • Altug Mert Sevim
  • Andrés de la Escosura
  • Tomás Torres
چکیده

Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 11 14  شماره 

صفحات  -

تاریخ انتشار 2013